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In addition, the total summed concentration of the 29 pesticides during winter (1037.60 ng L-1) was higher than summer (788.82 ng L-1) in rural and metropolitan areas. For the ecological risk assessments of fish, daphnia, and green algae, the triazoles, carbamates, neonicotinoids were risk-dominant pesticides, respectively. Notably, carbendazim had a 100% detection frequency and the highest concentration of the 29 pesticides analyzed, indicating its high consumption in the Huangpu River basin. This study aimed at investigating whether stable isotopes can be used to monitor the progress of volatile organic compounds (VOCs) volatilization from contaminated sediment during venting. Batches of a dry aquifer sediment were packed into stainless steel HPLC columns, humidified with distilled water and later contaminated by either liquid toluene or propan-2-ol. The VOCs were then volatilized by a stream of gas at room temperature, and the concentrations and stable isotope ratios of gaseous VOCs were recorded by isotope-ratio mass spectrometry. During early stages of volatilization of toluene, the isotope ratios Δδ13C shifted to more negative values by about -3 to -5‰ and the Δδ2H by more than -40‰, while the concentration remained at or near initial saturated vapor concentration. Depletion of the isotope ratios in the gas was explained by the vapor-liquid fractionation process, which is amplified by successive self-partitioning steps of gaseous VOC into remaining liquid VOC. For propan-2-ol the carbon isotope shift was negative like for toluene, whereas the H shift was positive. Hydrogen bonding in the liquid propan-2-ol phase causes a normal vapor-liquid H isotope effect which was described already in classical literature. The isotope shifts in the present experiments are larger than previously reported shifts due to phase-change processes and reach the magnitude of shifts usually observed in kinetic isotope fractionation. GW6471 A novel high-valent iron-oxo species (Fe(IV) = O) generated from Iron hexadecachlorophthalocyanine (FePcCl16)-mediated peroxymonosulfate (PMS) activation under visible light illumination for the degradation of a special group of compounds, indomethacine (IDM), containing methoxy, carboxyl, chloro, and amide groups was investigated. The experimental results indicate that Fe(IV) = O was able to selectively attack the carbonyl C-N bond on twisted amide groups, which exerts a strong toxic effect, and could therefore, effectively degrade and detoxify IDM and its byproducts. Twelve byproducts were identified by HPLC/MS/MS and calculation of frontier electron densities (FEDs), with all amide-group breakage products detected, and the possible pathways were deduced, which mainly consisted of Fe(IV) = O-induced cleavage of amide groups and radicals-induced reactions. Ecological risk assessment further confirmed a decrease in toxicity towards IDM degradation, which provides a promising Fe(IV) = O species for selective oxidation and detoxification of destabilized ground-state amides in drinking-water and wastewater treatment. Highly selective surface molecularly imprinted polymer (SMIP) was prepared on glucose-derived microporous carbon nanospheres (GMCNs) by surface molecular imprinting technology for the removal of phenol from wastewater. GMCNs with rich pore structure and surface oxygenic functional groups were adopted as support materials, on which the active layers were constructed by grafting silane coupling agent 3-(methacryloyloxy) propyltrimethoxysilane. Then with phenol as template molecule, different types and amounts of functional monomer (including methacrylic acid and 4-vinylpyridine (4-VP)) were screened for optimizing imprinting conditions suitable for phenol adsorption, and a series of SMIP was obtained through crosslinking polymerization. The adsorption behaviors of SMIP were evaluated by UV spectrophotometry. The results show that, when 4-VP is used as functional monomer, the resultant 4-VP/SMIP exhibites an excellent adsorption capacity of 85.72 mg g-1. The relative selectivity factor for phenol against hydroquinone, p-nitrophenol and p-tert-butylphenol is 8.38, 7.96 and 6.67, respectively, indicating outstanding adsorption capacity and selectivity of 4-VP/SMIP. The pseudo-second-order model and Langmuir‒Freundlich model fit better than other models for the adsorption of phenol. 4-VP/SMIP is promising for selective removal and enrichment recovery towards phenol in wastewater. Bombyx mori is an important economic insect. However, the environmental pollution caused by the widespread use of neonicotinoid insecticides has significantly affected the safe production of sericulture. In this paper, we determined the LC50 of acetamiprid, a kind of neonicotinoid insecticides, to 5th instar silkworm larvae, examined its residues in hemolymph and midgut of silkworm after continuous exposure to low-dose of acetamiprid, and investigated the transcription level of detoxifying-related genes and the activity of detoxifying enzymes. The results showed that acetamiprid was highly toxic (24-h LC50, 1.50 mg/L) to silkworm larvae. After continuous exposure to low-dose of acetamiprid (0.15 mg/L), the acetamiprid residue concentrations in hemolymph and midgut were 0.90 and 0.58 μg/mg, respectively, at 48 h, but all decreased at 96 h. At 24 h of acetamiprid exposure, the transcription levels of CYP4M5 and CYP6AB4 and the P450 enzyme activity were significantly enhanced. However, the transcription levels of CarE and CarE-11 and the activity of CarE enzymes were both inhibited by acetamiprid exposure. After 24 h-72 h of acetamiprid exposure, the transcription levels of GSTe3 and GSTd1 were significantly up-regulated, and the GST enzyme activity was also significantly elevated from 48 h to 96 h. Furthermore, the expression levels of FoxO, CncC and Keap1, the key upstream genes of detoxification enzymes, showed a similar trend as the GST genes. These results indicated that acetamiprid was reduced in midgut and the expression of GSTs was upregulated may via FoxO/CncC/Keap1 signaling pathway, which plays a key role in detoxification responses.