@fridayslave4
actief 6 uren, 50 minuten geleden
The less hindered steric environment with this conformation allows the benzylic group to bind to the Rh center in an η3 fashion, which stabilizes the C-B reductive elimination transition state. On the other hand, a pseudo-boat ligand conformation is involved in the selectivity-determining alkene migratory insertion step, where the more […] Bekijken
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Edwards McKinley heeft een update geplaatst 1 dag, 7 uren geleden
The less hindered steric environment with this conformation allows the benzylic group to bind to the Rh center in an η3 fashion, which stabilizes the C-B reductive elimination transition state. On the other hand, a pseudo-boat ligand conformation is involved in the selectivity-determining alkene migratory insertion step, where the more…[Lees meer]
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Edwards McKinley is geregistreerd lid geworden 3 dagen, 5 uren geleden
